作者:Suanon, F (Suanon, Fidele) ; Tang, L (Tang, Liu) ; Sheng, HJ (Sheng, Hongjie); Fu, YH (Fu, Yuhao) ; Xiang, LL (Xiang, Leilei); Wang, ZQ (Wang, Ziquan); Shao, XW (Shao, Xiangwen) ; Mama, D (Mama, Daouda) ; Jiang, X (Jiang, Xin) ; Wang, F (Wang, Fang)

题目：Organochlorine pesticides contaminated soil decontamination using TritonX-100-enhanced advanced oxidation under electrokinetic remediation

刊物：JOURNAL OF HAZARDOUS MATERIALS, 卷: 393     文献号: 122388

DOI: 10.1016/j.jhazmat.2020.122388

出版年: JUL 5 2020

下载链接：https://www.sciencedirect.com/science/article/pii/S0304389420303769?via%3Dihub

摘要： 

Remediation of organochlorine pesticides (OCPs)-contaminated soils is urgently required especially in China. Surfactants have emerged as reliable and efficient co-solvent for the treatment of hardly soluble organic pollutants in contaminated soil. Here, we report the use of TritonX-100 (TX-100) in advanced oxidation under electrokinetic technology (EK) for OCPs removal from a historically contaminated soil from a former pharmaceutical industrial wasteland. Result shows that TX-100 (10%) played a key role in soil remediation. In effect, after a treatment period of 15 days, pollutants washed ranged from 50.68% (4,4'-DDT) to 76.07% (HCB), when TX-100 was used as the electrolyte (EK-TX-100). A simple advanced oxidation of the soil using sodium persulfate (PS) under EK approach (EK-PS) was limited to achieve good removal efficiency of the pollutants; as the result of OCPs' hardly dissolvable nature. The achieved removal efficiency were comprised between 22.62% (2,4-DDT) and 55.78% (1,2,4,5-TCB). With the application of TX-100 as co-solvent (EK-TX-100/PS), the pollutants removal efficiency significantly improved (p < 0.05). The treatment efficiency was shifted and up to 88.05% (1,2,4-TCB) was achieved, while the lowest removal efficiency was 56.36% (4,4'-DDE). We come to the conclusion that the use of TX-100-enhanced advanced oxidation (EK-TX-100/PS) as a reliable treatment for remediating organochlorine contaminated soil.